 |
您当前的位置：网站首页→待发表文章→正文 |
| 第一次修改稿--钆内嵌金属富勒烯的制备、分离及质谱表征 |
| The Preparation and Separation of endohedral Gd-metallofullerene and MS Characterization |
| 作者： |
| 单位： |
| 中文摘要：利用自己设计的电弧炉，通过电弧放电法合成了内嵌金属富勒烯Gd@C82，研究并获得了制备钆金属富勒烯的最佳工艺条件：摩尔比Gd:C=1:15，电流I=90~100A，氦气压力0.08Mp；探讨并获得了Gd@C82新的萃取分离条件：常温下以DMF为溶剂，抽真空至压强为0.01Mp下萃取；探讨了内嵌金属富勒烯的生成和分离机理。 |
| 中文关键词：金属富勒烯 电弧放电 高效液相色谱 |
| 英文摘要： Metallofullerenes Gd @C82 was prepared by arc-discharge, and its best technological conditions are obtained: MGd: MC = 1:15, current I = 90 ~ 100A, helium pressure 0.08Mp. Extraction and separation conditions of metallofullerenes were studied, the soot was extracted in vacuum with DMF as the solvent at room temperature . And generation and separation mechanism of endohedral metallofullerenes were discussed. |
| 英文关键词：metallofullerene arc-discharge HPLC |